Dicarbonyl[4-(2,6-dimethylphenylamino)pent-3-en-2-onato-κ2 N,O]rhodium(I)
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چکیده
In the title compound, [Rh(C(13)H(16)NO)(CO)(2)], a square-planar coordination geometry is observed around the Rh(I) atom, formed by the N and O atoms of the bidentate ligand and two C atoms from two carbonyl ligands. The Rh(I) atom is displaced from the plane through these surrounding atoms by 0.0085 (2) Å. The dihedral angle between the benzene ring and the N-C-C-C-O plane is 89.82 (6)°, and the N-Rh-O bite angle for the bidentate ligand is 90.53 (6)°. An inter-molecular C-H⋯O inter-action is observed between a methyl group of the benzene ring and a carbonyl O atom.
منابع مشابه
Carbonyl[4-(2,3-dimethylphenylamino)pent-3-en-2-onato-κ2 N,O](triphenylphosphine-κP)rhodium(I)
In the title compound, [Rh(C(13)H(16)NO)(C(18)H(15)P)(CO)], the coordination geometry of the Rh(I) atom is square-planar, formed by the coordinating N and O atoms of the bidentate enaminoketonate ligand, one C atom from the carbonyl group and a P atom from triphenyl-phosphine. The complex displays a 0.591 (3):0.409 (3) ratio disorder of the phenyl unit of the monoanionic N,O-bidentate ligand. I...
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